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受限体系中柔性高分子链的熵随机共振。

Entropic stochastic resonance of a flexible polymer chain in a confined system.

机构信息

Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.

出版信息

J Chem Phys. 2012 Jul 28;137(4):044904. doi: 10.1063/1.4737638.

Abstract

We have studied the dynamics of a flexible polymer chain in constrained dumb-bell-shape geometry subject to a periodic force and external noise along the longitudinal direction. It is found that the system exhibits a feature of entropic stochastic resonance (ESR), i.e., the temporal coherence of the polymer motion can reach a maximum level for an optimal noise intensity. We demonstrate that the occurrence of ESR is robust to the change of chain length, while the bottleneck width should be properly chosen. A gravity force in the vertical direction is not necessary for the ESR here, however, the elastic coupling between polymer beads is crucial.

摘要

我们研究了在沿纵向周期性力和外部噪声的约束哑铃形状几何结构中柔性聚合物链的动力学。结果发现,系统表现出熵随机共振(ESR)的特征,即聚合物运动的时间相干性可以达到最佳噪声强度下的最大水平。我们证明了 ESR 的发生对链长的变化具有鲁棒性,而瓶颈宽度应该适当选择。此处不需要垂直方向的重力来产生 ESR,但是聚合物珠之间的弹性耦合是至关重要的。

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