Dalton Trans. 2012 Oct 7;41(37):11259-62. doi: 10.1039/c2dt31076g. Epub 2012 Aug 1.
The reactions of an S-bridged trinuclear palladium(II) complex, [Pd(3)(D-pen-N,O,S)(3)] (D-H(2)pen = D-penicillamine), with ethylenediamine (en) and racemic (R,R/S,S) 1,2-cyclohexanediamine (chxn) in water gave mononuclear palladium(II) complexes, [Pd(D-pen-N,S)(en)] (1) and [Pd(D-pen-N,S)(chxn)] (2), respectively. Of two diastereomers, [Pd(D-pen-N,S)(R,R-chxn)] (2(R)) and [Pd(D-pen-N,S)(S,S-chxn)] (2(S)), possible for 2, 2(S) was exclusively isolated in a high yield.
S-桥联三核钯（II）配合物[Pd(3)(D-pen-N,O,S)(3)]（D-H(2)pen=D-青霉胺）与乙二胺（en）和外消旋（R,R/S,S）1,2-环己二胺（chxn）在水中反应，分别得到单核钯（II）配合物[Pd(D-pen-N,S)(en)]（1）和[Pd(D-pen-N,S)(chxn)]（2）。在两种非对映异构体[Pd(D-pen-N,S)(R,R-chxn)]（2(R)）和[Pd(D-pen-N,S)(S,S-chxn)]（2(S)）中，可能的 2,2(S)以高产率被选择性地分离出来。
