State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing 210093, People's Republic of China.
Inorg Chem. 2012 Aug 20;51(16):8649-51. doi: 10.1021/ic3012475. Epub 2012 Aug 3.
Two new enantiomeric ionic chiral dysprosium(III) compounds were designed and synthesized. These compounds show simultaneously the optical activity, ferroelectric effects, nonlinear-optical effects, and slow magnetic relaxation behavior. More interestingly, these compounds exhibit reversible single-crystal-to-single-crystal transformations associated with the release or absorption of solvent molecules. The structure transformations are accompanied by distinct changes in the physical properties.
两种新的对映离子手性镝（III）化合物被设计和合成。这些化合物同时表现出光学活性、铁电效应、非线性光学效应和慢磁弛豫行为。更有趣的是，这些化合物表现出与溶剂分子的释放或吸收相关的可逆单晶到单晶转变。结构转变伴随着物理性质的明显变化。
