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直接用卟啉剥离石墨,制备功能化的纳米石墨烯杂化物。

Direct exfoliation of graphite with a porphyrin--creating functionalizable nanographene hybrids.

机构信息

Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, 91058 Erlangen, Germany.

出版信息

Chem Commun (Camb). 2012 Sep 11;48(70):8745-7. doi: 10.1039/c2cc32888g.

DOI:10.1039/c2cc32888g
PMID:22863974
Abstract

Exfoliation of graphite was achieved using a free-base porphyrin 1 resulting in an efficient fabrication of single-layer nanographene (NG)- hybrid platelets that can be further functionalized with other nanomaterials. The novel nanographene-porphyrin hybrids reveal efficient charge transfer in the excited state.

摘要

通过使用自由碱基卟啉 1 实现石墨的剥落,从而有效地制备了可以进一步用其他纳米材料官能化的单层纳米石墨烯(NG)-杂化片。新型的纳米石墨烯-卟啉杂化物在激发态下表现出有效的电荷转移。

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