N-杂环硼烷：用于II型光聚合反应的耐空气和耐水共引发剂。
NHC-boranes: air- and water-tolerant co-initiators for type II photopolymerizations.
作者信息
Lacôte Emmanuel, Curran Dennis P, Lalevée Jacques
机构信息
ICSN CNRS, Av. de la Terrasse, F-91198 Gif s/Yvette Cedex, France.
出版信息
Chimia (Aarau). 2012;66(6):382-5. doi: 10.2533/chimia.2012.382.
PMID:22871279
Abstract
N-Hetereocyclic carbene (NHC) complexes of boranes are stable compounds that can be used as co-initiators for the type II photopolymerization of acrylates. The present account summarizes this new development for polymerization and boron chemistry. In particular, NHC-boranes are air- and water-tolerant, which enhances the practicality of the photopolymerizations.
摘要
硼烷的N-杂环卡宾（NHC）配合物是稳定的化合物，可用作丙烯酸酯类II型光聚合的共引发剂。本综述总结了聚合反应和硼化学领域的这一最新进展。特别是，NHC-硼烷具有空气和水耐受性，这提高了光聚合反应的实用性。
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