钯催化的未活化碘代烷基的原子转移自由基环化反应。
Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide.
机构信息
Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Lu, Shanhai 200062, PR China.
出版信息
Org Biomol Chem. 2012 Sep 28;10(36):7274-7. doi: 10.1039/c2ob25990g.
PMID:22886029
Abstract
A palladium-catalyzed atom transfer cyclization of unactivated alkyl iodide has been developed. A radical chain mechanism has been proposed for this transformation, which might not involve an alkylpalladium intermediate.
摘要
发展了一种钯催化的未活化碘代烷基的原子转移环化反应。该转化提出了自由基链式机理，可能不涉及烷基钯中间体。
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