Department of Chemistry, University of Illinois at Chicago, 845 W. Taylor Street, Chicago, IL, 60607-7061, USA.
Angew Chem Int Ed Engl. 2018 Mar 1;57(10):2712-2715. doi: 10.1002/anie.201712775. Epub 2018 Feb 6.
A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo- and heterocyclic structures.
发展了一种新型温和、可见光诱导的钯催化氢原子迁移/原子转移自由基环化(HAT/ATRC)级联反应。该方案涉及先前未知的杂化乙烯基钯自由基中间体的 1,5-HAT 过程,从而得到碘甲基碳环和杂环结构。