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东爱琴海海洋有机污染物:坎达利湾表层沉积物中的脂肪族和多环芳烃。

Marine organic pollutants of the Eastern Aegean: aliphatic and polycyclic aromatic hydrocarbons in Candarli Gulf surficial sediments.

机构信息

Dokuz Eylul University, Institute of Marine Sciences & Technology, Inciralti, 35340 Izmir, Turkey.

出版信息

Mar Pollut Bull. 2012 Nov;64(11):2569-75. doi: 10.1016/j.marpolbul.2012.07.019. Epub 2012 Aug 11.

Abstract

Aliphatics and PAHs were determined in sediments from the Candarli Gulf in 2009. Aliphatics ranged from 3.88 to 24.7 μg g(-1) while aromatics varied between <4.15 and 405 ng g(-1) (dw). PAHs ranged from a relatively low to a moderate PAHs pollution compared to other urbanized coastal areas worldwide. 3-ring PAHs were most abundant in the sampling area. Both pyrolytic and petrogenic PAHs were present in most samples, although petroleum derived PAHs were dominant at the stations situated near the refinery and petrochemical, metal industry and pyrolytic sources were mainly prevalent in the estuary of Bakircay River. The ratio of UCM to n-alkanes and CPI values in station 6 indicate that the main contribution to petroleum hydrocarbon contamination is via oil and its products. PAH levels at all sites were below the ERL and ERM except fluorene. The results indicated that the sediments should have no potential biological impact except stations 6 and 14.

摘要

2009 年,对坎达利湾的沉积物进行了脂肪族化合物和多环芳烃(PAHs)的检测。脂肪族化合物的浓度范围为 3.88 至 24.7μg/g(干重),而芳香族化合物的浓度范围为 <4.15 至 405ng/g(干重)。与世界上其他城市化沿海地区相比,多环芳烃的污染程度处于较低到中等水平。在采样区域,三环多环芳烃最为丰富。大多数样品中存在热解和生源多环芳烃,但在靠近炼油厂和石化、金属工业的站点,石油衍生的多环芳烃占主导地位,而在巴克里卡伊河河口,主要存在热解源。站点 6 中 UCM 与正构烷烃的比值和 CPI 值表明,石油烃污染的主要来源是石油及其产品。除芴外,所有站点的多环芳烃水平均低于 ERM 和 ERL。结果表明,除站点 6 和 14 外,其余站点的沉积物可能不会产生潜在的生物影响。

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