Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, CAS Middle Tian Road, 18, Lanzhou, China.
Chem Commun (Camb). 2012 Sep 28;48(75):9391-3. doi: 10.1039/c2cc34178f. Epub 2012 Aug 15.
A highly efficient Au/Ag-Mo nano-rods catalyst was prepared for the one-pot synthesis of imine and amine using equal molar ratio of nitrobenzene and alcohol as starting materials, and bio-based glycerol as the hydrogen source. The reaction mechanism of the nitrobenzene reduction, amine and aldehyde coupling, and imine reduction was explored.
一种高效的 Au/Ag-Mo 纳米棒催化剂被制备用于以等摩尔比的硝基苯和醇作为起始原料、以生物基甘油作为氢源一锅合成亚胺和胺。探讨了硝基苯还原、胺和醛偶联以及亚胺还原的反应机制。