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金/银-钼纳米棒催化硝基苯和醇类化合物的还原偶联反应,使用甘油作为氢源。

Au/Ag-Mo nano-rods catalyzed reductive coupling of nitrobenzenes and alcohols using glycerol as the hydrogen source.

机构信息

Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, CAS Middle Tian Road, 18, Lanzhou, China.

出版信息

Chem Commun (Camb). 2012 Sep 28;48(75):9391-3. doi: 10.1039/c2cc34178f. Epub 2012 Aug 15.

Abstract

A highly efficient Au/Ag-Mo nano-rods catalyst was prepared for the one-pot synthesis of imine and amine using equal molar ratio of nitrobenzene and alcohol as starting materials, and bio-based glycerol as the hydrogen source. The reaction mechanism of the nitrobenzene reduction, amine and aldehyde coupling, and imine reduction was explored.

摘要

一种高效的 Au/Ag-Mo 纳米棒催化剂被制备用于以等摩尔比的硝基苯和醇作为起始原料、以生物基甘油作为氢源一锅合成亚胺和胺。探讨了硝基苯还原、胺和醛偶联以及亚胺还原的反应机制。

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