二碘代{2-[(4-甲氧基-苯基)亚氨基甲基]吡啶-κ(2)N,N'}锌
Diiodido{2-[(4-meth-oxy-phen-yl)imino-meth-yl]pyridine-κ(2)N,N'}zinc.
作者信息
Salehzadeh Sadegh, Khalaj Mehdi, Dehghanpour Saeed
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1041. doi: 10.1107/S1600536812030486. Epub 2012 Jul 10.
Abstract
In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra-hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C-H⋯I and C-H⋯O hydrogen bonds are observed, in addition to π-π stacking inter-actions, with a centroid-centroid distance of 3.72 (5) Å.
摘要
在标题配合物[ZnI₂(C₁₃H₁₂N₂O)]中，Zn(II)原子具有扭曲的四面体配位构型。有机配体为双齿配体，通过两个N原子与Zn(II)原子配位。苯环和吡啶环的二面角为11.67 (9)°。在晶体中，除了质心间距为3.72 (5) Å的π-π堆积相互作用外，还观察到弱的C-H⋯I和C-H⋯O氢键。
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