二碘代{4-硝基-2-[2-(哌啶-1-基)乙基-亚氨基-甲基]苯酚根合}锌(II)
Diiodido{4-nitro-2-[2-(piperidin-1-yl)ethyl-imino-meth-yl]phenolato}zinc(II).
作者信息
Zhu Xue-Wen, Yang Xu-Zhao, Zhang Chun-Xia, Li Gang-Sen, Yin Zhi-Gang
机构信息
Key Laboratory of Surface and Interface Science of Henan, School of Material & Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1332-3. doi: 10.1107/S1600536809040495.
In the title complex, [ZnI(2)(C(14)H(19)N(3)O(3))], the Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two iodide ions in a distorted tetra-hedral coordination. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming dimers.
在标题配合物[ZnI₂(C₁₄H₁₉N₃O₃)]中，Zn(II)原子由席夫碱配体的亚胺N原子和酚盐O原子以及两个碘离子以扭曲的四面体配位方式进行四配位。在晶体结构中，分子通过分子间的N-H⋯O氢键相连，形成二聚体。
Zotero 插件