{4,4',6,6'-四碘-2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合-κ(4)O,N,N',O'}镍(II)
{4,4',6,6'-Tetra-iodo-2,2'-[propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(4)O,N,N',O'}nickel(II).
作者信息
Kargar Hadi, Kia Reza, Adabi Ardakani Amir, Tahir Muhammad Nawaz
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1090. doi: 10.1107/S1600536812032138. Epub 2012 Jul 18.
The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant inter-molecular inter-actions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944 (1):0.056 (1).
标题化合物[Ni(C₁₇H₁₂I₄N₂O₂)]的不对称单元包含一个席夫碱配合物的一半。镍(II)和丙基链的中心碳原子位于二重旋转轴上。镍(II)原子周围的几何构型为平面正方形，由配位配体的N₂O₂供体原子支撑。在晶体中，不存在显著的分子间相互作用。所研究的晶体为非等轴孪晶，孪晶组分比经精修后为0.944 (1):0.056 (1)。
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