二水合-[(1R,2S,4R,8R,9S,11R)-2,9-二甲基-1,4,8,11-四氮杂环十四烷]二氯化镍(II)二水合物
Diaqua-[(1R,2S,4R,8R,9S,11R)-2,9-di-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane]nickel(II) dichloride dihydrate.
作者信息
Townsend James Alan, Desper John
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1111-2. doi: 10.1107/S160053681203276X. Epub 2012 Jul 25.
Abstract
The crystal structure of the title complex, [Ni(C(12)H(28)N(4))(H(2)O)(2)]Cl(2)·2H(2)O, displays O-H⋯Cl and O-H⋯O hydrogen bonding. The tetra-aza-cyclo-tetra-decane ligand inter-acts with the Ni(II) atom in the cis V configuration and the final two ligand binding sites are occupied by water.
摘要
标题配合物[Ni(C₁₂H₂₈N₄)(H₂O)₂]Cl₂·2H₂O的晶体结构显示出O-H⋯Cl和O-H⋯O氢键。四氮杂环十四烷配体以顺式V构型与Ni(II)原子相互作用，最后两个配体结合位点被水占据。
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