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双{6-溴-4-氯-2-[(E)-(2-氯苯基)-亚氨基甲基]苯酚根合-κ(2)N,O}铜(II)

Bis{6-bromo-4-chloro-2-[(E)-(2-chloro-phenyl)-imino-meth-yl]-phenolato-κ(2)N,O}copper(II).

作者信息

Ping Zhang

机构信息

Department of Chemistry, Xianyang Normal University, Xianyang, Shaanxi 712000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1118. doi: 10.1107/S1600536812025044. Epub 2012 Jul 25.

DOI:10.1107/S1600536812025044
PMID:22904769
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414162/
Abstract

In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL(2) {where HL= 2-[(E)-(2-chloro-phenyl-imino)-meth-yl]-6-bromo-4-chloro-phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol-ecules are linked via Cu⋯Cl inter-actions [2.9933 (11) Å], forming a two-dimensional network parallel to the bc plane. They are also Cl⋯Cl inter-actions [3.3709 (14) Å] present, which consolidate the two-dimensional network structure.

摘要

在标题化合物[Cu(C₁₃H₇BrCl₂NO)₂]，即CuL₂{其中HL = 2-[(E)-(2-氯-苯基亚氨基)-甲基]-6-溴-4-氯苯酚}中，Cu(II)原子位于一个对称中心上，具有平面正方形配位。在晶体中，配合物分子通过Cu⋯Cl相互作用[2.9933 (11) Å]相连，形成一个平行于bc平面的二维网络。还存在Cl⋯Cl相互作用[3.3709 (14) Å]，这巩固了二维网络结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7af/3414162/1f281a366be4/e-68-m1118-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7af/3414162/bc2b9ffcbcac/e-68-m1118-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7af/3414162/1f281a366be4/e-68-m1118-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7af/3414162/bc2b9ffcbcac/e-68-m1118-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7af/3414162/1f281a366be4/e-68-m1118-fig2.jpg

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