氯代{4-氯-2-[(2-吗啉代乙基)亚氨基甲基]苯酚根-κN,N',O}铜(II)
Chlorido{4-chloro-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato-κN,N',O}copper(II).
作者信息
Ikmal Hisham Nurul Azimah, Mohd Ali Hapipah, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 4;65(Pt 8):m870. doi: 10.1107/S1600536809025215.
The Cu(II) atom in the title compound, [Cu(C(13)H(16)ClN(2)O(2))Cl], exists in a distorted square-planar coordination environment as the deprotonated Schiff base chelates to the Cu(II) atom through three atom sites. In the crystal structure, adjacent mol-ecules are linked by a Cu⋯Cl [3.011 (1) Å] bridge, generating a linear chain running along the b axis of the ortho-rhom-bic unit cell.
在标题化合物[Cu(C₁₃H₁₆ClN₂O₂)Cl]中，Cu(II)原子处于扭曲的平面正方形配位环境中，因为去质子化的席夫碱通过三个原子位点与Cu(II)原子螯合。在晶体结构中，相邻分子通过Cu⋯Cl [3.011 (1) Å]桥相连，形成一条沿正交晶胞b轴延伸的线性链。
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