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4-{[(1S,2R)-2-羟基茚满-1-基]氨基}-3-戊烯-2-酮

4-{[(1S,2R)-2-Hy-droxy-indan-1-yl]amino}-pent-3-en-2-one.

作者信息

Park Ka Hyun, Go Min Jeong, Lee Hwi Hyun, Kim Sungae, Lee Junseong

机构信息

Department of Chemistry, Chonnam National University, Gwangju 500-757, Republic of Korea.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2455. doi: 10.1107/S1600536812031169. Epub 2012 Jul 14.

DOI:10.1107/S1600536812031169
PMID:22904899
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414912/
Abstract

In the mol-ecule of the title compound, C(14)H(17)NO(2), the dihedral angle formed by the mean planes through the indan ring system and the amino-pentenone fragment is 83.26 (13)°. An intra-molecular N-H⋯O hydrogen bond is observed. In the crystal, mol-ecules are linked into one-dimensional chains extending along the [010] direction via O-H⋯O and C-H⋯O hydrogen bonds.

摘要

在标题化合物C₁₄H₁₇NO₂的分子中，通过茚满环系和氨基戊烯酮片段的平均平面所形成的二面角为83.26（13）°。观察到分子内存在N-H⋯O氢键。在晶体中，分子通过O-H⋯O和C-H⋯O氢键连接成沿[010]方向延伸的一维链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d8/3414912/579584d94ced/e-68-o2455-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d8/3414912/80b7fbbea0c7/e-68-o2455-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d8/3414912/579584d94ced/e-68-o2455-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d8/3414912/80b7fbbea0c7/e-68-o2455-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d8/3414912/579584d94ced/e-68-o2455-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Novel chlorotitanium complexes containing chiral tridentate schiff base ligands for ring-opening polymerization of lactide.含手性三齿席夫碱配体的新型氯钛配合物用于丙交酯的开环聚合反应
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Bis(acetylacetonato)tricarbonyl tungsten(II): a convenient precursor to chiral bis(acac) tungsten(II) complexes.
双（乙酰丙酮）三羰基钨（II）：一种制备手性双（乙酰丙酮）钨（II）配合物的便捷前体。
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Isovalent and mixed-valent diruthenium complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = acetylacetonate and bpytz = 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): synthesis, spectroelectrochemical, and epr investigation .同价和混合价态的二钌配合物[(acac)2RuII (-bpytz)RuII(acac)2]和[(acac)2RuII(-bpytz)RuIII(acac)2](ClO4)（acac = 乙酰丙酮，bpytz = 3,6-双(3,5-二甲基吡唑基)-1,2,4,5-四嗪）：合成、光谱电化学及电子顺磁共振研究
Inorg Chem. 2004 Sep 20;43(19):6108-13. doi: 10.1021/ic049346r.