2,3,5-三苯基-2H-四唑-3-鎓四苯基硼酸盐
2,3,5-Triphenyl-2H-tetra-zol-3-ium tetra-phenyl-borate.
作者信息
Fun Hoong-Kun, Chia Tze Shyang, Mostafa Gamal A E, Hefnawy Mohamed M, Abdel-Aziz Hatem A
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2567. doi: 10.1107/S1600536812032941. Epub 2012 Jul 28.
Abstract
In the title salt, C(19)H(15)N(4) (+)·C(24)H(20)B(-), the tetra-phenyl-borate anion is in a tetra-hedral geometry around the B atom [C-B-C angles of 107.10 (9)-111.79 (9)°]. In the cation, the tetra-zole ring makes dihedral angles of 3.04 (7), 51.75 (7) and 51.13 (7)° with the attached phenyl rings. In the crystal, C-H⋯π inter-actions link the cations and anions into ion pairs.
摘要
在标题盐C(19)H(15)N(4) (+)·C(24)H(20)B(-)中，四苯基硼酸根阴离子在硼原子周围呈四面体几何构型[C - B - C角为107.10 (9)-111.79 (9)°]。在阳离子中，四唑环与相连的苯环形成的二面角分别为3.04 (7)、51.75 (7)和51.13 (7)°。在晶体中，C - H⋯π相互作用将阳离子和阴离子连接成离子对。
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