• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2,3,5-三苯基-2H-四唑-3-鎓四苯基硼酸盐

2,3,5-Triphenyl-2H-tetra-zol-3-ium tetra-phenyl-borate.

作者信息

Fun Hoong-Kun, Chia Tze Shyang, Mostafa Gamal A E, Hefnawy Mohamed M, Abdel-Aziz Hatem A

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2567. doi: 10.1107/S1600536812032941. Epub 2012 Jul 28.

DOI:10.1107/S1600536812032941
PMID:22904995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3415008/
Abstract

In the title salt, C(19)H(15)N(4) (+)·C(24)H(20)B(-), the tetra-phenyl-borate anion is in a tetra-hedral geometry around the B atom [C-B-C angles of 107.10 (9)-111.79 (9)°]. In the cation, the tetra-zole ring makes dihedral angles of 3.04 (7), 51.75 (7) and 51.13 (7)° with the attached phenyl rings. In the crystal, C-H⋯π inter-actions link the cations and anions into ion pairs.

摘要

在标题盐C(19)H(15)N(4) (+)·C(24)H(20)B(-)中，四苯基硼酸根阴离子在硼原子周围呈四面体几何构型[C - B - C角为107.10 (9)-111.79 (9)°]。在阳离子中，四唑环与相连的苯环形成的二面角分别为3.04 (7)、51.75 (7)和51.13 (7)°。在晶体中，C - H⋯π相互作用将阳离子和阴离子连接成离子对。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c85d/3415008/f05cc85818b3/e-68-o2567-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c85d/3415008/f05cc85818b3/e-68-o2567-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c85d/3415008/f05cc85818b3/e-68-o2567-fig1.jpg

相似文献

1
2,3,5-Triphenyl-2H-tetra-zol-3-ium tetra-phenyl-borate.2,3,5-三苯基-2H-四唑-3-鎓四苯基硼酸盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2567. doi: 10.1107/S1600536812032941. Epub 2012 Jul 28.
2
2,3,5-Triphenyl-2H-tetra-zol-3-ium iodide.2,3,5-三苯基-2H-四唑-3-碘化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2621. doi: 10.1107/S1600536812033661. Epub 2012 Aug 1.
3
2,3,5-Triphenyl-2H-tetra-zol-3-ium bromide ethanol monosolvate.2,3,5-三苯基-2H-四唑-3-溴化铵乙醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2566. doi: 10.1107/S1600536812032953. Epub 2012 Jul 28.
4
Crystal structure of 2-di-methyl-amino-1-eth-oxy-carbonyl-3-methyl-3,4,5,6-tetra-hydro-pyrimidin-1-ium tetra-phenyl-borate.2-二甲基氨基-1-乙氧基羰基-3-甲基-3,4,5,6-四氢嘧啶-1-鎓四苯基硼酸盐的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Oct 31;71(Pt 11):o894-5. doi: 10.1107/S2056989015020034. eCollection 2015 Nov 1.
5
Bis(2-amino-1,3-benzothia-zol-3-ium) tetra-chloridozincate(II).二氯锌酸双（2-氨基-1,3-苯并噻唑-3-鎓）（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m654-5. doi: 10.1107/S1600536811015753. Epub 2011 May 7.
6
Bis(2-amino-4-phenyl-1,3-thia-zol-3-ium) tetra-chlorido-palladate(II).二氯·双（2-氨基-4-苯基-1,3-噻唑-3-鎓）钯（II）
Acta Crystallogr Sect E Struct Rep Online. 2014 Jul 11;70(Pt 8):m295. doi: 10.1107/S1600536814015360. eCollection 2014 Aug 1.
7
Crystal structure of N''-(2-eth-oxy-2-oxoeth-yl)-N,N,N',N'-tetra-methyl-N''-[3-(1,3,3-tri-methyl-ureido)prop-yl]guanidinium tetra-phenyl-borate.四苯基硼酸N''-(2-乙氧基-2-氧代乙基)-N,N,N',N'-四甲基-N''-[3-(1,3,3-三甲基脲基)丙基]胍盐的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Dec 9;71(Pt 12):o1026-7. doi: 10.1107/S2056989015023142. eCollection 2015 Dec 1.
8
[3-(Dimethyl-amino)benzoato]triphenyl-tin(IV).[3 -（二甲基氨基）苯甲酸根合]三苯基锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):m1530-1. doi: 10.1107/S1600536808036337.
9
Crystal structure of N-[3-(di-methyl-amino)-prop-yl]-N',N',N'',N''-tetra-methyl-N-(N,N,N',N'-tetra-methyl-form-amid-in-ium-yl)guanidinium bis-(tetra-phenyl-borate).N-[3-(二甲基氨基)丙基]-N',N',N'',N''-四甲基-N-(N,N,N',N'-四甲基甲脒鎓基)胍双(四苯基硼酸盐)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Dec 12;71(Pt 12):o1045-6. doi: 10.1107/S2056989015023336. eCollection 2015 Dec 1.
10
3-(1H-Tetra-zol-5-yl)pyridinium 3-(2H-tetra-zol-5-yl)pyridinium dinitrate.3 -（1H - 四唑 - 5 - 基）吡啶鎓 3 -（2H - 四唑 - 5 - 基）吡啶鎓二硝酸盐
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):o1684. doi: 10.1107/S160053680901839X.

本文引用的文献

1
Septonex-tetraphenylborate screen-printed ion selective electrode for the potentiometric determination of Septonex in pharmaceutical preparations.用于药物制剂中 Septonex 的电位测定的 Septonex-四苯硼酸盐丝网印刷离子选择性电极。
Analyst. 2011 Apr 7;136(7):1488-95. doi: 10.1039/c0an00662a. Epub 2011 Feb 2.
2
Potentiometric determination of cetylpyridinium chloride using a new type of screen-printed ion selective electrodes.采用新型丝网印刷离子选择性电极测定十六烷基吡啶氯。
Anal Chim Acta. 2010 Jul 12;673(1):79-87. doi: 10.1016/j.aca.2010.05.016. Epub 2010 May 20.
3
Structure validation in chemical crystallography.
化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
4
Characteristics of new composite- and classical potentiometric sensors for the determination of pioglitazone in some pharmaceutical formulations.用于测定某些药物制剂中吡格列酮的新型复合和经典电位传感器的特性
J Pharm Biomed Anal. 2008 Sep 10;48(1):57-61. doi: 10.1016/j.jpba.2008.04.029. Epub 2008 May 7.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.