Daniewski Włodzimierz Maria, Danikiewicz Witold, Gołebiewski W Marek, Gucma Mirosław, Łysik Agnieszka, Grodner Jacek, Przybysz Elzbieta
lnstitute of Organic Chemistry, Polish Academy of Science, Kasprzaka 44/52, 01-224 Warsaw, Poland.
Nat Prod Commun. 2012 Jul;7(7):917-8.
Ground fruit bodies of Cantharellus cibarius (chanterelle) were extracted with dichloromethane and subjected to CC followed by preparative HPLC, which led to the isolation of glycerol 1,2- and 1,3-dilinoleates and glycerol tridehydrocrepenynate. Extraction of C. cibarius fruit bodies with ethanol or methanol afforded fatty acid ethyl or methyl esters as a result of esterification/transesterification reactions. Insecticidal activity of the isolated glycerides and esters was much lower than that of the crude extracts and chromatographic fractions suggesting a synergistic effect of some of the compounds present in the mixture.
用二氯甲烷提取鸡油菌(美味牛肝菌)的子实体,然后进行柱色谱,接着进行制备型高效液相色谱,从而分离出甘油1,2-二亚油酸酯、甘油1,3-二亚油酸酯和甘油三脱氢crepenynate。用乙醇或甲醇提取鸡油菌子实体,由于发生酯化/酯交换反应,得到了脂肪酸乙酯或甲酯。分离出的甘油酯和酯的杀虫活性远低于粗提物和色谱馏分,这表明混合物中某些化合物具有协同作用。