苯并咪唑基阴离子受体对乳酸表现出选择性，而对丙酮酸则没有。
Benzimidazole-based anion receptors exhibiting selectivity for lactate over pyruvate.
机构信息
Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
出版信息
Org Biomol Chem. 2012 Oct 14;10(38):7780-8. doi: 10.1039/c2ob26299a.
PMID:22911002
Abstract
The influence of anions on tautomerism in benzimidazole containing anion receptors has been studied via a variety of techniques in both solution and the solid state. The results show that hydrogen bonding interactions between the receptors and guests have a significant effect of the nature of the tautomer present. The compounds show a preference for complexation of lactate over pyruvate.
摘要
通过在溶液和固态中使用各种技术，研究了阴离子对含苯并咪唑的阴离子受体的互变异构的影响。结果表明，受体和客体之间的氢键相互作用对存在的互变异构体的性质有重大影响。这些化合物表现出对乳酸盐的络合偏好，而不是丙酮酸。
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