College of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, Henan Normal University, Xinxiang 453007, Henan, China.
Chem Commun (Camb). 2012 Oct 9;48(78):9723-5. doi: 10.1039/c2cc35309a.
Metal-catalyzed direct C(sp(3))-H bond amination of 2-alkyl azaarenes with N=N double bonds has been developed, which expands the scope of C(sp(3))-H bond activation reactions and provides a new access to medicinally important azaarene derivatives.
金属催化的带有 N=N 双键的 2-烷基氮杂芳烃的直接 C(sp(3))-H 键胺化反应已经被开发出来,这拓展了 C(sp(3))-H 键活化反应的范围,并为具有重要药用价值的氮杂芳烃衍生物提供了新的途径。