Environmental Pollution Control Laboratory, Chemistry Department, Aristotle University of Thessaloniki, 54 124 Thessaloniki, Greece.
Mar Pollut Bull. 2012 Nov;64(11):2443-52. doi: 10.1016/j.marpolbul.2012.07.048. Epub 2012 Aug 23.
An integrated study was conducted to determine the presence of phenolic and steroid endocrine-disrupting compounds (EDCs), in the marine environment of Thermaikos Gulf, Northern Aegean Sea, Greece. Seawater, suspended particulate matter, sediments and biota were examined for nonylphenol, octylphenol, their mono- and diethoxylate oligomers, bisphenol A, estrone, 17α-estradiol, 17β-estradiol, estriol, mestranol and 17 α -ethynylestradiol. Phenolic compounds were detected in all of the compartments, with nonylphenol and its ethoxylates being the dominant pollutants. The occurrence of nonylphenol in sediments presents a significant risk to the biota. Mussels exhibited relatively low concentrations and low bioconcentration factors for NP and OP. The effect of terrestrial sources of the EDCs on the marine environment is discussed. The influence of suspended particulate matter and organic carbon in the partition of the EDCs between the dissolved and the particulate phase was investigated.
对希腊北爱琴 Thermaikos 湾的海洋环境中存在的酚类和类固醇类内分泌干扰化合物(EDCs)进行了综合研究。对海水、悬浮颗粒物、沉积物和生物群进行了壬基酚、辛基酚、单和双乙氧基化低聚物、双酚 A、雌酮、17α-雌二醇、17β-雌二醇、雌三醇、孕马雌酮和 17α-乙炔基雌二醇的检测。所有隔室中均检测到酚类化合物,其中壬基酚及其乙氧基化物是主要污染物。沉积物中壬基酚的存在对生物群构成重大风险。贻贝对 NP 和 OP 的浓度相对较低,生物浓缩系数也较低。讨论了 EDCs 的陆地来源对海洋环境的影响。还研究了悬浮颗粒物和有机碳对 EDCs 在溶解相与颗粒相之间分配的影响。