Macromolecular Science and Engineering, University of Michigan, 2300 Hayward Ave., Ann Arbor, Michigan 48109-2136, USA.
Chem Commun (Camb). 2012 Oct 11;48(79):9828-30. doi: 10.1039/c2cc34689c. Epub 2012 Aug 29.
The synthesis and successful activation of IRMOF-8 (Zn(4)O(ndc)(3), ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO(2) yields a guest-free material with a BET surface area of 4461 m(2) g(-1).
介绍了 IRMOF-8（Zn(4)O(ndc)(3)，ndc = 萘-2,6-二羧酸）的合成和成功活化。室温合成有效地抑制了互贯。虽然在减压下的传统活化导致结构坍塌，但通过流动超临界 CO(2)的活化得到了一种无客体的材料，其 BET 比表面积为 4461 m(2) g(-1)。
