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使用甘油作为氢源，通过可回收磁性铁氧体-镍纳米粒子（Fe(3)O(4)-Ni）实现对硝基芳烃和羰基化合物的区域和化学选择性还原。

Regio- and chemoselective reduction of nitroarenes and carbonyl compounds over recyclable magnetic ferrite-nickel nanoparticles (Fe(3)O(4)-Ni) by using glycerol as a hydrogen source.

机构信息

REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Portugal.

出版信息

Chemistry. 2012 Oct 1;18(40):12628-32. doi: 10.1002/chem.201202380. Epub 2012 Aug 30.

DOI:10.1002/chem.201202380
PMID:22933355
Abstract

Reduction by magnetic nano-Fe(3)O(4)-Ni: a facile, simple and environmentally friendly hydrogen-transfer reaction that takes place over recyclable ferrite-nickel magnetic nanoparticles (Fe(3)O(4)-Ni) by using glycerol as hydrogen source allows aromatic amines and alcohols to be synthesized from the precursor nitroarenes and carbonyl compounds.

摘要

通过磁纳米 Fe(3)O(4)-Ni 的还原作用：使用甘油作为氢源，在可回收的铁氧体-镍磁性纳米粒子 (Fe(3)O(4)-Ni) 上进行的一种简便、简单且环保的氢转移反应，允许芳族胺和醇由前体硝基芳烃和羰基化合物合成。

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