使用甘油作为氢源，通过可回收磁性铁氧体-镍纳米粒子（Fe(3)O(4)-Ni）实现对硝基芳烃和羰基化合物的区域和化学选择性还原。
Regio- and chemoselective reduction of nitroarenes and carbonyl compounds over recyclable magnetic ferrite-nickel nanoparticles (Fe(3)O(4)-Ni) by using glycerol as a hydrogen source.
机构信息
REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Portugal.
出版信息
Chemistry. 2012 Oct 1;18(40):12628-32. doi: 10.1002/chem.201202380. Epub 2012 Aug 30.
PMID:22933355
Abstract
Reduction by magnetic nano-Fe(3)O(4)-Ni: a facile, simple and environmentally friendly hydrogen-transfer reaction that takes place over recyclable ferrite-nickel magnetic nanoparticles (Fe(3)O(4)-Ni) by using glycerol as hydrogen source allows aromatic amines and alcohols to be synthesized from the precursor nitroarenes and carbonyl compounds.
摘要
通过磁纳米 Fe(3)O(4)-Ni 的还原作用：使用甘油作为氢源，在可回收的铁氧体-镍磁性纳米粒子 (Fe(3)O(4)-Ni) 上进行的一种简便、简单且环保的氢转移反应，允许芳族胺和醇由前体硝基芳烃和羰基化合物合成。
Zotero 插件