Department of Chemistry, College of Chemistry and Chemical Engineering, and State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, China.
Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9838-41. doi: 10.1002/anie.201204073. Epub 2012 Aug 31.
Building bridges: The first m-metallapyridine and the first metallapyridyne were synthesized under mild reaction conditions. The two complexes are metal-bridged polycyclic metallabenzenoid aromatics, in which the transition-metal center is shared by both six-membered rings. The synthetic method permits the use of metallabenzene as a starting material to access higher π-electron metallaaromatics.
首次在温和的反应条件下合成了第一个 m-金属吡啶和第一个金属吡啶炔。这两个配合物是金属桥联的多环金属苯并芳烃，其中过渡金属中心被两个六元环共享。该合成方法允许使用金属苯作为起始原料来获得具有更高π电子的金属芳烃。
