Department of Food Science and Technology, Universidade Estadual de Londrina, Rodovia Celso Garcia Cid (PR 445), Km 380, P.O. Box 6001, CEP 86051-990 Londrina, PR, Brazil.
Carbohydr Polym. 2012 Nov 6;90(4):1452-60. doi: 10.1016/j.carbpol.2012.07.015. Epub 2012 Jul 14.
Starch extruded in the presence of a plasticizer results in a material called thermoplastic starch (TPS). TPS mixed with poly(butylene adipate co-terephthalate) (PBAT), soybean oil (SO), and surfactant may result in films with improved mechanical properties due to greater hydrophobicity and compatibility among the polymers. This study characterized films produced from blends containing 65% TPS and 35% PBAT with SO added as compatibilizer. The Tween 80 was added to prevention of phase separation. The elongation and resistance were greater in the films with SO. The infrared spectra confirmed an increase in ester groups bonded to the PBAT and the presence of groups bonded to the starch ring, indicating TPS-SO and PBAT-SO interactions. The micrographs suggest that the films with SO were more homogenous. Thus, SO is considered to be a good compatibilizer for blends of TPS and PBAT.
在增塑剂存在的情况下挤压淀粉会得到一种称为热塑性淀粉(TPS)的材料。TPS 与聚(丁二酸丁二醇酯-co-对苯二甲酸丁二醇酯)(PBAT)、大豆油(SO)和表面活性剂混合,由于聚合物之间的疏水性和相容性增加,可能会导致具有改善机械性能的薄膜。本研究对含有 65%TPS 和 35%PBAT 的共混物制成的薄膜进行了表征,SO 作为增容剂添加。添加吐温 80 以防止相分离。添加 SO 的薄膜具有更大的伸长率和阻力。红外光谱证实与 PBAT 键合的酯基增加,并且存在与淀粉环键合的基团,表明 TPS-SO 和 PBAT-SO 相互作用。显微照片表明含有 SO 的薄膜更加均匀。因此,SO 被认为是 TPS 和 PBAT 共混物的良好增容剂。