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用于高效薄膜硅太阳能电池的石墨烯透明电极的光捕获设计

Light-trapping design of graphene transparent electrodes for efficient thin-film silicon solar cells.

作者信息

Zhao Yongxiang, Chen Fei, Shen Qiang, Zhang Lianmeng

机构信息

School of Bafang Logistics, Fuzhou University, Fuzhou 350108, China.

出版信息

Appl Opt. 2012 Sep 1;51(25):6245-51. doi: 10.1364/AO.51.006245.

Abstract

In this paper, the performance of solar cells with graphene transparent electrodes is compared with cells using conventional indium tin oxide (ITO) electrodes, and it is demonstrated the optical absorption of solar cells with bare graphene structure is worse than that of bare ITO structure because of the higher refractive index of graphene. To enhance the light trapping of graphene-based thin-film solar cells, a simple two-layer SiO(2)/SiC structure is proposed as antireflection coatings deposited on top of graphene transparent electrodes, and the thickness of each layer is optimized by differential evolution in order to enhance the optical absorption of a-Si:H thin-film solar cells to the greatest degree. The optimization results demonstrate the optimal SiO(2)/SiC/graphene structure can obtain 37.30% enhancement with respect to bare ITO structure, which has obviously exceeded the light-trapping enhancement of 34.15% for the optimal SiO(2)/SiC/ITO structure. Therefore, with the aid of the light-trapping structure, the graphene films are a very promising indium-free transparent electrode substitute for the conventional ITO electrode for use in cost-efficient thin-film silicon solar cells.

摘要

在本文中,将具有石墨烯透明电极的太阳能电池的性能与使用传统铟锡氧化物(ITO)电极的电池进行了比较,结果表明,由于石墨烯的折射率较高,具有裸石墨烯结构的太阳能电池的光吸收比裸ITO结构的要差。为了增强基于石墨烯的薄膜太阳能电池的光捕获能力,提出了一种简单的双层SiO(2)/SiC结构作为沉积在石墨烯透明电极顶部的抗反射涂层,并通过差分进化对每层的厚度进行了优化,以最大程度地提高非晶硅氢化薄膜太阳能电池的光吸收。优化结果表明,相对于裸ITO结构,最佳的SiO(2)/SiC/石墨烯结构可提高37.30%,这明显超过了最佳SiO(2)/SiC/ITO结构34.15%的光捕获增强效果。因此,借助光捕获结构,石墨烯薄膜是一种非常有前途的无铟透明电极替代品,可用于具有成本效益的薄膜硅太阳能电池中替代传统的ITO电极。

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