一锅法合成苯并[1,4]噻嗪-3(4H)-酮及 S-N 型 Smiles 重排反应机理的理论研究。
One-pot synthesis of benzo[1,4]thiazin-3(4H)-ones and a Theoretical Study of the S-N type Smiles rearrangement mechanism.
机构信息
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China.
出版信息
J Org Chem. 2012 Oct 5;77(19):8501-6. doi: 10.1021/jo3014287. Epub 2012 Sep 14.
PMID:22950354
Abstract
Benzo[1,4]thiazin-3(4H)-one derivatives are conveniently prepared in one pot via a Smiles rearrangement (SR) tandem reaction. In order to understand the reaction, we present here a theoretical study on the S-N type SR mechanism.
摘要
苯并[1,4]噻嗪-3(4H)-酮衍生物可通过 Smiles 重排（SR）串联反应方便地一锅法制备。为了理解该反应，我们在此提出了对 S-N 型 SR 机理的理论研究。
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