Department of Physics and William Mong Institute of Nano Science and Technology, HKUST, Clear Water Bay, Kowloon, Hong Kong, China.
Sci Rep. 2012;2:625. doi: 10.1038/srep00625. Epub 2012 Sep 3.
We present electrical and thermal specific heat measurements that show superconductivity in double-wall carbon nanotube (DWCNT) bundles. Clear evidence, comprising a resistance drop as a function of temperature, magnetoresistance and differential resistance signature of the supercurrent, suggest an intrinsic superconducting transition below 6.8 K for one particular sample. Additional electrical data not only confirm the existence of superconductivity, but also indicate the T(c) distribution that can arise from the diversity in the diameter and chirality of the DWCNTs. A broad superconducting anomaly is observed in the specific heat of a bulk DWCNT sample, which yields a T(c) distribution that correlates well with the range of the distribution obtained from the electrical data. As quasi one dimensionality of the DWCNTs dictates the existence of electronic density of state peaks, confirmation of superconductivity in this material system opens the exciting possibility of tuning the T(c) through the application of a gate voltage.
我们呈现了电和热比热测量结果,表明了双壁碳纳米管(DWCNT)束中的超导性。明确的证据包括电阻随温度的下降、超导电流的磁阻和微分电阻特征,表明一个特定样品的超导转变温度低于 6.8 K。额外的电学数据不仅证实了超导性的存在,还表明了 T(c)分布可能源于 DWCNTs 的直径和手性多样性。在 bulk DWCNT 样品的比热中观察到一个宽的超导异常,这产生了一个与从电学数据中获得的分布范围很好相关的 T(c)分布。由于 DWCNTs 的准一维性决定了电子态密度峰的存在,这种材料系统中超导性的确认开辟了通过施加栅极电压来调节 T(c)的令人兴奋的可能性。