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用于热电应用的非化学计量比 Cu(2)ZnSnSe(4) 纳米晶的大规模胶体合成。

Large-scale colloidal synthesis of non-stoichiometric Cu(2) ZnSnSe(4) nanocrystals for thermoelectric applications.

机构信息

Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, the National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026, P.R. China.

出版信息

Adv Mater. 2012 Dec 4;24(46):6158-63. doi: 10.1002/adma.201202860. Epub 2012 Sep 10.

Abstract

Over 10 g of non-stoichiometric Cu(2) ZnSnSe(4) colloidal nanocrystals for thermoelectric applications are prepared after one single reaction. The obtained pellet made from the colloidal nanocrystals shows a peak ZT value of 0.44 at 450 °C, which is similar to those of state-of-the-art Cu(2) ZnSnSe(4) -based bulk materials at the same temperature.

摘要

经单次反应可制备超过 10 g 的非化学计量比 Cu(2) ZnSnSe(4) 胶体纳米晶,用于热电应用。由胶体纳米晶制成的压坯在 450°C 时表现出 0.44 的峰值 ZT 值,与同一温度下的先进 Cu(2) ZnSnSe(4) 基块状材料相当。

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