Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, PR China.
Nanoscale. 2012 Oct 21;4(20):6244-55. doi: 10.1039/c2nr31929b.
Recent advances in wet chemical synthesis of magnetically recyclable nanocatalysts (MRNCs), a versatile integration of high catalytic activity and facile recovery, have led to a dramatic expansion of their potential applications. This review focuses on the recent work in the development of metal and metal oxide based MRNCs for catalytic conversion of organic compounds in solution phase. This will be discussed in detail, according to the two main synthesis methods of MRNCs as classified by us. The two methods are: template-assisted synthetic strategy and direct synthetic strategy. And the template-assisted synthesis is further divided into three subcategories, synthetic strategies assisted by hard-, soft-, and mixed hard-soft coupling layers. At the end, we outline future trends and perspectives in these research areas.
磁性可回收纳米催化剂(MRNCs)的湿化学合成的最新进展,将高催化活性和易于回收的优点完美结合,极大地扩展了其潜在应用。本综述重点介绍了用于溶液相中有机化合物催化转化的基于金属和金属氧化物的 MRNC 的最新开发工作。根据我们分类的 MRNC 的两种主要合成方法,将对此进行详细讨论。这两种方法是:模板辅助合成策略和直接合成策略。模板辅助合成进一步分为三种亚类,分别是由硬模板、软模板和软硬混合模板辅助的合成策略。最后,我们概述了这些研究领域的未来趋势和前景。