Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, USA.
Inorg Chem. 2012 Oct 1;51(19):10071-3. doi: 10.1021/ic301228j. Epub 2012 Sep 11.
Two trifunctional ligands built from enantiopure amino acids and containing a 1,8-naphthalimide group have been used to prepare two new complexes of potassium that have extended structures based on homochiral-rod secondary building units. One structure is a three-dimensional metal-organic framework (MOF), while the other is a two-dimensional solid that is organized into a supramolecular MOF by strong π···π-stacking interactions of the naphthalimide groups in the third dimension.
两种由手性氨基酸构建的三功能配体，且均含有 1,8-萘酰亚胺基团，被用于合成两种基于手性棒状次级构筑单元的新型钾配合物。其中一种结构是三维金属有机骨架（MOF），另一种是二维固体，通过萘酰亚胺基团在第三维上的强π···π堆积作用，被组织成超分子 MOF。
