具有协同自旋转变的梯型铁(II)配位聚合物。
A ladder type iron(II) coordination polymer with cooperative spin transition.
机构信息
Inorganic Chemistry II, Universität Bayreuth, Universitätsstrasse 30, NW 1, 95440 Bayreuth, Germany.
出版信息
Chem Commun (Camb). 2012 Oct 21;48(82):10222-4. doi: 10.1039/c2cc35109a.
PMID:22968447
Abstract
Ladder type 1D coordination polymers were synthesised with the aim to improve the spin crossover properties of the iron(II) complexes following the concepts of crystal engineering. A wide hysteresis loop (34 K) was observed if rigid linkers were used. The first X-ray structure for a 1D iron(II) ladder is reported.
摘要
梯型 1D 配位聚合物的合成目的是通过晶体工程的概念来改善铁(II)配合物的自旋交叉性质。如果使用刚性连接体，则会观察到宽滞后环（34 K）。报道了首例 1D 铁(II)梯型的 X 射线结构。
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