Institut de Ciència Molecular (ICMol)/Departament de Química Inorgànica, Universitat de València, C/ Catedrático José Beltrán Martínez 2, 46980 Paterna, València, Spain.
Inorg Chem. 2013 Jan 7;52(1):3-5. doi: 10.1021/ic301639r. Epub 2012 Dec 21.
In this Communication, we report the synthesis and characterization of novel Hofmann-like spin-crossover porous coordination polymers of composition {Fe(L)[M(CN)(4)]}·G [L = 1,4-bis(4-pyridylethynyl)benzene and M(II) = Ni, Pd, and Pt]. The spin-crossover properties of the framework are closely related to the number and nature of the guest molecules included in the pores.
在本通讯中，我们报告了新型霍夫曼型自旋交叉多孔配位聚合物的合成与表征，其组成为{Fe(L)[M(CN)(4)]}·G [L = 1,4-双(4-吡啶基乙炔基)苯，M(II) = Ni、Pd 和 Pt]。骨架的自旋交叉性质与包含在孔中的客体分子的数量和性质密切相关。
