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catena-Poly[disilver(I)(Ag-Ag)-bis-(μ(3)-quinoline-3-carboxyl-ato)-1:2:1'κ(3)O:O':N;2:1'':2''κ(3)N:O:O'].

作者信息

Liu Chun-Bo, Cong Yao, Sun He-Yi

机构信息

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1177. doi: 10.1107/S1600536812035209. Epub 2012 Aug 15.

DOI:10.1107/S1600536812035209
PMID:22969472
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435599/
Abstract

In the title compound, Ag(2)(C(10)H(6)NO(2))(2), the Ag(I) atom is coordinated by one N atom and two O atoms from three quinoline-3-carboxyl-ate ligands in a T-shaped fashion, with an additional Ag⋯Ag distance of 2.9468 (6) Å. The ligands connect the Ag(I) atoms into a double-chain structure along [010]. Weak Ag⋯O inter-actions [Ag⋯O = 2.802 (3) and 2.877 (4) Å] link the double-chains into a layer network parallel to (101). π-π inter-actions are also observed in the layer network [centroid-centroid distances = 3.780 (3) and 3.777 (3) Å].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93aa/3435599/74ed816fa9ab/e-68-m1177-fig1.jpg

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