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二氯双{1-[(2-甲基-苯并咪唑-1-基-κN(3))甲基]苯并三唑}锌

Dichloridobis{1-[(2-methyl-benzimidazol-1-yl-κN(3))meth-yl]benzotriazole}zinc.

作者信息

Song Lianqing, Zhao Meihong, Cui Guoshi, Gao Jianghua, Lin Lin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1179. doi: 10.1107/S160053681203526X. Epub 2012 Aug 15.

DOI:10.1107/S160053681203526X
PMID:22969474
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435601/
Abstract

The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra-hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crystal, complex mol-ecules are extended by inter-molecular π-π inter-actions [centroid-centroid distance = 3.792 (2) Å] into a three-dimensional supra-molecular network.

摘要

标题单核锌（II）配合物[ZnCl₂(C₁₅H₁₃N₅)₂]与先前报道的汞（II）配合物同型。锌（II）原子位于二重旋转轴上，具有由两个氯原子和来自两个杂环配体的两个氮原子构成的扭曲四面体环境。在晶体中，配合物分子通过分子间π-π相互作用[质心-质心距离 = 3.792 (2) Å]扩展成三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6968/3435601/37b4a722768b/e-68-m1179-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6968/3435601/4af705702d15/e-68-m1179-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6968/3435601/37b4a722768b/e-68-m1179-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6968/3435601/4af705702d15/e-68-m1179-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6968/3435601/37b4a722768b/e-68-m1179-fig2.jpg

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本文引用的文献

1
Dichloridobis[1-(2-methyl-benzimidazol-1-ylmethyl-κN)benzotriazole]mercury(II).二氯双[1-(2-甲基-苯并咪唑-1-基甲基-κN)苯并三唑]汞(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m829. doi: 10.1107/S1600536809023459.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Ligand-directed molecular architectures: self-assembly of two-dimensional rectangular metallacycles and three-dimensional trigonal or tetragonal prisms.
配体导向的分子结构：二维矩形金属环和三维三角或四方棱柱的自组装。
J Am Chem Soc. 2003 Jul 16;125(28):8595-613. doi: 10.1021/ja034267k.