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具有弱软化核的二维粒子流体中的六方相和类水异常。

Hexatic phase and water-like anomalies in a two-dimensional fluid of particles with a weakly softened core.

机构信息

Dipartimento di Fisica, Università degli Studi di Messina, Contrada Papardo, 98166 Messina, Italy.

出版信息

J Chem Phys. 2012 Sep 14;137(10):104503. doi: 10.1063/1.4749260.

Abstract

We study a two-dimensional fluid of particles interacting through a spherically symmetric and marginally soft two-body repulsion. This model can exist in three different crystal phases, one of them with square symmetry and the other two triangular. We show that, while the triangular solids first melt into a hexatic fluid, the square solid is directly transformed on heating into an isotropic fluid through a first-order transition, with no intermediate tetratic phase. In the low-pressure triangular and square crystals, melting is reentrant provided the temperature is not too low, but without the necessity of two competing nearest-neighbor distances over a range of pressures. A whole spectrum of water-like fluid anomalies completes the picture for this model potential.

摘要

我们研究了一种通过球形对称和边缘柔软的两体排斥相互作用的二维粒子流体。该模型可以存在于三种不同的晶体相中,其中一种具有正方形对称性,另外两种具有三角形对称性。我们表明,尽管三角形固体首先熔化成六方流体,但正方形固体在加热时通过一级相变直接转化为各向同性流体,没有中间的四元相。在低压三角形和正方形晶体中,只要温度不是太低,熔化就会重新出现,但不需要在一定压力范围内存在两种竞争的最近邻距离。对于这个模型势,完整的水状流体异常谱完成了这幅图景。

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