Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, F-67000, Strasbourg, France.
Chem Commun (Camb). 2012 Oct 25;48(83):10313-5. doi: 10.1039/c2cc35543d.
An imidazole-appended dipyrrin ligand yields, upon coordination to Cu(II) cations, a linear metallatecton that self-assembles with Cd(II) salts to afford 2D grid-type MOFs which, upon parallel stacking, lead to porous crystals offering 1D channels.
一个咪唑取代的二吡咯配体与 Cu(II) 阳离子配位,生成一个线性的金属构筑单元,该构筑单元与 Cd(II) 盐自组装,形成 2D 网格型 MOFs,这些 MOFs 平行堆积,形成具有 1D 通道的多孔晶体。