Park Young S, Holmes Mark J, Taylor Robert A, Kim Kwang S, Lee Seung-Woong, Ju HaeRi, Im Hyunsik
Clarendon Laboratory, Department of Physics, University of Oxford, Oxford, OX1 3PU, UK.
Nanotechnology. 2012 Oct 12;23(40):405602. doi: 10.1088/0957-4484/23/40/405602. Epub 2012 Sep 14.
Semiconductor nanopyramids (NPs) provide advantages in the development of novel functional optoelectronic devices due to their unique size-dependent properties. Here we demonstrate a new method for the fabrication of selectively self-assembled single-crystalline GaN NPs on the m-plane of periodically strained GaN/InGaN multiquantum disks embedded in the middle of GaN nanorods. The GaN NPs, which have ~100 nm diameters and heights, are observed by scanning electron microscopy and their crystalline structure is confirmed by high-resolution transmission electron microscopy. Experimental analysis directly reveals the strain distribution along the growth direction of the NPs. Cathodoluminescence measurements on a single NP show that its emission energy redshifts compared with that of bulk GaN, corroborating the results showing the formation of tensile strain in the NP. Observations of the uniform distribution and localization of these NPs show the possibility of further tuning their size and density by controlling periodically strained nanorod surfaces.
半导体纳米金字塔(NPs)因其独特的尺寸依赖性特性,在新型功能性光电器件的开发中具有优势。在此,我们展示了一种新方法,用于在嵌入氮化镓纳米棒中间的周期性应变氮化镓/铟镓氮多量子盘的m平面上制备选择性自组装的单晶氮化镓纳米金字塔。通过扫描电子显微镜观察到直径和高度约为100nm的氮化镓纳米金字塔,并通过高分辨率透射电子显微镜确认其晶体结构。实验分析直接揭示了纳米金字塔生长方向上的应变分布。对单个纳米金字塔的阴极发光测量表明,其发射能量相对于体相氮化镓发生红移,这证实了纳米金字塔中形成拉伸应变的结果。对这些纳米金字塔的均匀分布和定位的观察表明,通过控制周期性应变的纳米棒表面,有可能进一步调整它们的尺寸和密度。