Bio-energy Corporation, Research and Development Laboratory, 2-9-7 Minaminanamatsu, Amagasaki 660-0053, Japan.
Bioresour Technol. 2013 May;135:386-95. doi: 10.1016/j.biortech.2012.08.014. Epub 2012 Aug 10.
The increased global demand for biofuels has prompted the search for alternatives to edible oils for biodiesel production. Given the abundance and cost, waste and nonedible oils have been investigated as potential feedstocks. A recent research interest is the conversion of such feedstocks into biodiesel via enzymatic processes, which have considerable advantages over conventional alkali-catalyzed processes. To expand the viability of enzymatic biodiesel production, considerable effort has been directed toward process development in terms of biodiesel productivity, application to wide ranges of contents of water and fatty acids, adding value to glycerol byproducts, and bioreactor design. A cost evaluation suggested that, with the current enzyme prices, the cost of catalysts alone is not competitive against that of alkalis. However, it can also be expected that further process optimization will lead to a reduced cost in enzyme preparation as well as in downstream processes.
全球对生物燃料的需求不断增加,促使人们寻找可替代食用油来生产生物柴油的方法。鉴于其丰富的储量和低廉的成本,人们已经研究了将废弃油脂和不可食用油作为潜在原料来生产生物柴油。最近,人们对通过酶法工艺将这些原料转化为生物柴油产生了浓厚的兴趣,与传统的碱催化工艺相比,这种方法具有明显的优势。为了扩大酶法生物柴油生产的可行性,研究人员在提高生物柴油的生产效率、拓宽水和脂肪酸含量适用范围、提高甘油副产物附加值以及生物反应器设计等方面进行了大量的工艺开发工作。成本评估表明,以目前的酶价计算,仅催化剂的成本就无法与碱法竞争。然而,人们也期望进一步的工艺优化将降低酶制剂和下游处理过程的成本。