观察非血红素铁催化烯烃和烷烃与 O2 反应时形成的过氧铁氢氧化物配合物。
Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2.
机构信息
Auburn University, Department of Chemistry and Biochemistry, Auburn, AL 36849, USA.
出版信息
Chem Commun (Camb). 2012 Nov 4;48(85):10532-4. doi: 10.1039/c2cc34634f.
PMID:22992783
Abstract
A non-heme iron complex catalyses the oxidation of allylic, benzylic, and aliphatic C-H bonds by O(2). During this reactivity, a ferric hydroperoxide species is observed. The kinetic analysis of this complex's formation may suggest a ferric superoxo species as the initial metal-based oxidant.
摘要
一种非血红素铁配合物通过 O(2)催化烯丙基、苄基和脂肪族 C-H 键的氧化。在这种反应性中，观察到了一种铁过氧氢物种。对该配合物形成的动力学分析可能表明铁过氧物种是初始金属基氧化剂。
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