Dipartimento di Ingegneria dell'Innovazione, Università del Salento, Via per Monteroni, Edificio Corpo O, 73100 Lecce, Italy.
Phys Rev Lett. 2012 May 18;108(20):207803. doi: 10.1103/PhysRevLett.108.207803.
When nematic liquid crystals are constrained to a curved surface, the geometry induces distortions in the molecular orientation. The mechanisms of the geometrical frustration involve the intrinsic as well as the extrinsic geometry of the underlying substrate. We show that the nematic elastic energy promotes the alignment of the flux lines of the nematic director towards geodesics and/or lines of curvature of the surface. As a consequence, the influence of the curvature can be tuned through the Frank elastic moduli. To illustrate this effect, we consider the simple case of nematics lying on a cylindrical shell. By combining the curvature effects with external magnetic fields, the molecular alignment can be reoriented or switched between two stable configurations. This enables the manipulation of nematic alignment for the design of new materials and technological devices.
当向列液晶被限制在一个曲面上时,几何形状会导致分子取向的扭曲。几何约束的机制涉及到基底的内在和外在几何形状。我们表明,向列弹性能量促进向列指向矢的通量线朝着测地线和/或曲面的曲率线对齐。因此,曲率的影响可以通过弗兰克弹性模量来调节。为了说明这种效应,我们考虑了向列液晶在圆柱壳上的简单情况。通过将曲率效应与外部磁场结合,可以重新定向或在两种稳定构型之间切换分子取向。这使得可以操纵向列液晶的取向,以设计新材料和技术设备。