Department of Chemistry, University of Zululand, KwaDlangezwa 3886, South Africa.
Colloids Surf B Biointerfaces. 2013 Jan 1;101:450-6. doi: 10.1016/j.colsurfb.2012.07.010. Epub 2012 Jul 28.
Cysteine and triethanolamine capped CdTe nanoparticles have been synthesized using a simple aqueous solution based method. This method involves the reaction of tellurium powder with sodium borohydride (NaBH(4)) in water to produce telluride ions (Te(2-)), followed by the simultaneous addition of an aqueous solution of cadmium chloride or other cadmium source (acetate, carbonate and nitrate) and solution of L-cysteine ethyl ester hydrochloride or triethanolamine. The effect of capping agent on the size, structure and morphology of the as-synthesized nanoparticles was investigated. The particles were characterized using optical spectroscopy, transmission electron microscopy (TEM), high-resolution TEM (HRTEM), X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy.
半胱氨酸和三乙醇胺封端的 CdTe 纳米粒子已通过一种简单的基于水溶液的方法合成。该方法涉及在水中使碲粉与硼氢化钠(NaBH(4))反应生成碲化物离子(Te(2-)),然后同时加入氯化镉或其他镉源(醋酸盐、碳酸盐和硝酸盐)的水溶液和 L-半胱氨酸乙酯盐酸盐或三乙醇胺的溶液。考察了封端剂对所合成的纳米粒子的尺寸、结构和形态的影响。使用光学光谱、透射电子显微镜(TEM)、高分辨率 TEM(HRTEM)、X 射线衍射(XRD)和傅里叶变换红外(FT-IR)光谱对颗粒进行了表征。