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使用巯基乙酸、巯基甘油和 L-半胱氨酸合成碲化镉纳米粒子。

Synthesis of Cadmium Telluride Nanoparticles Using Thioglycolic Acid, Thioglycerol, and L-Cysteine.

机构信息

School of Chemical and Materials Engineering, Korea National University of Transportation, Chungju, Chungbuk 27469, Republic of Korea.

Graduate School of Transportation, Korea National University of Transportation, Uiwang, Gyeonggi 16106, Republic of Korea; and Department of Information Technology and Energy Convergence, Korea National University of Transportation, Chungju, Chungbuk 27469, Republic of Korea.

出版信息

J Nanosci Nanotechnol. 2021 Jul 1;21(7):4073-4076. doi: 10.1166/jnn.2021.19182.

Abstract

Cadmium telluride (CdTe) nanoparticles (NPs) are known for their unique physical and chemical properties. NP synthesis via a size-controlled procedure has become an intriguing research topic because NPs exhibit novel optical and physical properties depending on their size. Their sizes and properties can vary depending on the types and concentrations of stabilizers, which are bound to the surface of the NPs and protect the NPs from aggregation. In this study, we synthesized CdTe NPs stabilized by thioglycolic acid (TGA), 1-thioglycerol (TGC), and L-cysteine (L-C). The ratio of stabilizer to Cd was 1:2.4. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and photoluminescence (PL) were employed for characterization of the NPs. The average sizes of the synthesized NPs were 4.2, 4.1, and 3.7 nm for TGA, TGC, and L-C, respectively. The maximum fluorescent emission peaks of the three NP solutions were at 554.9, 551.6, and 538.3 nm for TGA, TGC, and L-C, respectively. The produced particles were crystalline in structure with a face-centered cubic (fcc) system.

摘要

碲化镉(CdTe)纳米粒子(NPs)以其独特的物理和化学性质而闻名。通过尺寸控制程序合成 NPs 已成为一个有趣的研究课题,因为 NPs 的尺寸决定了它们具有新颖的光学和物理性质。它们的大小和性质可以根据稳定剂的类型和浓度而变化,稳定剂结合在 NPs 的表面,防止 NPs 聚集。在这项研究中,我们使用巯基乙酸(TGA)、1-巯基甘油(TGC)和 L-半胱氨酸(L-C)稳定合成了 CdTe NPs。稳定剂与 Cd 的比例为 1:2.4。我们使用透射电子显微镜(TEM)、X 射线衍射(XRD)和光致发光(PL)对 NPs 进行了表征。合成的 NPs 的平均尺寸分别为 TGA、TGC 和 L-C 的 4.2nm、4.1nm 和 3.7nm。三种 NP 溶液的最大荧光发射峰分别为 TGA、TGC 和 L-C 的 554.9nm、551.6nm 和 538.3nm。所制备的颗粒具有面心立方(fcc)体系的结晶结构。

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