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利用再生聚丙烯-丙烯酸接枝无纺材料去除水中的油。

Utilization of recycled polypropylene-acrylate grafted nonwoven for the removal of oil from water.

机构信息

State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Tianjin Polytechnic University, Tianjin 300387, China.

出版信息

Water Environ Res. 2012 Sep;84(9):719-24. doi: 10.2175/106143012x13373550426913.

Abstract

To solve water pollution caused by oil spillage, a new sorbent was prepared by radiation-induced graft polymerization. Acrylate monomer was introduced to polypropylene nonwoven and hydrophobic groups were introduced by the grafting method. The grafting degree of sorbent was determined as a function of monomer concentration and solvent solubility for monomer. Fourier transform-infrared spectra and static contact angle measurements were used to characterize the chemical changes of the polypropylene nonwoven surface. The grafted sorbent showed a fast sorption rate and a maximum sorption capacity of 13.56 g/g for diesel oil, while the original polypropylene nonwoven was only 7.48 g/g. In addition, retention measurement and the reusability test were conducted to evaluate the suitability of the polypropylene-acrylate grafted nonwoven for the treatment of oil spillage.

摘要

为了解决溢油造成的水污染问题,采用辐射接枝聚合的方法制备了一种新型吸附剂。将丙烯酸酯单体引入到聚丙烯无纺材料中,并通过接枝法引入疏油基团。吸附剂的接枝程度取决于单体浓度和单体在溶剂中的溶解度。傅里叶变换红外光谱和静态接触角测量用于表征聚丙烯无纺材料表面的化学变化。接枝后的吸附剂对柴油的吸附速率很快,最大吸附容量为 13.56 g/g,而原始的聚丙烯无纺材料仅为 7.48 g/g。此外,还进行了保留量测定和可重复使用性测试,以评估聚丙烯-丙烯酸酯接枝无纺材料用于处理溢油的适用性。

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