氮氧自由基 XIII 的反应：使用 4-丙烯酰氧基-2,2,6,6-四甲基哌啶-1-氧自由基作为起始化合物，DABCO 和奎宁环作为催化剂，合成含氮氧自由基部分的 Morita-Baylis-Hillman 加合物。
Reactions of nitroxides XIII: Synthesis of the Morita-Baylis-Hillman adducts bearing a nitroxyl moiety using 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl as a starting compound, and DABCO and quinuclidine as catalysts.
机构信息
Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland.
出版信息
Beilstein J Org Chem. 2012;8:1515-22. doi: 10.3762/bjoc.8.171. Epub 2012 Sep 12.
Abstract
The Morita-Baylis-Hillman adducts bearing a nitroxyl moiety were synthesized from 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl and aliphatic, aryl and heterocyclic aldehydes.
摘要
具有硝酮部分的 Morita-Baylis-Hillman 加合物是由 4-丙烯酰氧基-2,2,6,6-四甲基哌啶-1-氧自由基和脂肪族、芳族和杂环醛合成的。
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