通过卤素键将 DABCO 氟标记化：用于 Morita-Baylis-Hillman 反应的可回收催化剂。
Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita-Baylis-Hillman reaction.
机构信息
Laboratoire BioCIS-CNRS, Faculté de Pharmacie, Univ Paris Sud, 5 rue J.B. Clément, F-92296, Châtenay-Malabry, France.
出版信息
Chem Commun (Camb). 2011 May 28;47(20):5855-7. doi: 10.1039/c1cc10869g. Epub 2011 Apr 15.
PMID:21494739
Abstract
The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO·(C(8)F(17)I)(2)) acts as a recyclable organocatalyst for the Morita-Baylis-Hillman reaction. This "supramolecular fluorous catalyst" is readily accessible and can be recovered by simple precipitation/filtration.
摘要
DABCO 与两个全氟辛基碘分子的卤键加合物（DABCO·(C(8)F(17)I)(2)）可用作 Morita-Baylis-Hillman 反应的可回收有机催化剂。这种“超分子氟相催化剂”易于获得，可通过简单的沉淀/过滤回收。
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