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基于室温软化学策略的具有优异短路电流的混合太阳能电池:以 P3HT:Ag2S 为例。

Hybrid solar cells with outstanding short-circuit currents based on a room temperature soft-chemical strategy: the case of P3HT:Ag2S.

机构信息

Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province and Institute of Surface Micro and Nano Materials, Xuchang University, Henan 461000, China.

出版信息

J Am Chem Soc. 2012 Oct 24;134(42):17392-5. doi: 10.1021/ja307521t. Epub 2012 Oct 11.

Abstract

P3HT:Ag(2)S hybrid solar cells with broad absorption from the UV to NIR band were directly fabricated on ITO glass by using a room temperature, low energy consumption, and low-cost soft-chemical strategy. The resulting Ag(2)S nanosheet arrays facilitate the construction of a perfect percolation structure with organic P3HT to form ordered bulk heterojunctions (BHJ); without interface modification, the assembled P3HT:Ag(2)S device exhibits outstanding short-circuit current densities (J(sc)) around 20 mA cm(-2). At the current stage, the optimized device exhibited a power conversion efficiency of 2.04%.

摘要

P3HT:Ag(2)S 杂化太阳能电池在 UV 至近红外波段具有宽吸收,通过使用室温下、低能耗和低成本的软化学策略,可直接在 ITO 玻璃上制备。所得的 Ag(2)S 纳米片阵列有助于与有机 P3HT 构建完美的渗流结构,形成有序的体异质结 (BHJ);无需界面修饰,组装的 P3HT:Ag(2)S 器件的短路电流密度 (J(sc))高达约 20 mA cm(-2)。在现阶段,优化后的器件表现出 2.04%的功率转换效率。

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