Laboratory of Molecular Recognition and synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.
Org Biomol Chem. 2013 Jan 7;11(1):98-109. doi: 10.1039/c2ob26365c.
In this paper, LB-Phos·HBF(4) salt has been applied for the Pd-catalysed Suzuki coupling reactions of optically active (Z)-α-choroalkylidene-β-lactones. Aryl, vinyl, alkyl and heteroaromatic boronic acids may be coupled with optically active β-lactones affording corresponding optically active products highly selectively and efficiently.
在本文中，LB-Phos·HBF(4)盐被应用于 Pd 催化的手性 (Z)-α-氯代亚烷基-β-内酰胺的Suzuki 偶联反应。芳基、乙烯基、烷基和杂芳基硼酸可以与手性β-内酰胺偶联，高选择性和高效率地得到相应的手性产物。
