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[用于在参考浓度水平下测定空气中物质——深度石油加工危险生产(环氧乙烷、1,3 - 丁二烯)标志物的方法的开发]

[Development of the method for determining substances--markers of the hazardous production of advanced oil processing (ethylene oxide, 1,3-butadiene) in the air at the level of reference concentrations].

出版信息

Gig Sanit. 2012 Jul-Aug(4):78-82.

Abstract

The results of experimental studies on the development of gas chromatographic method for the determination of 1,3-butadiene and ethylene oxide in ambient air at the level of reference concentration with the use of sorption of the compounds studied from ambient air on the adsorbent TenaxTA in conjunction with optimum conditions of thermal desorption and the use of capillary gas chromatography are presented. The parameters of adsorption, thermal desorption and gas chromatographic determination of 1,3-butadiene and ethylene oxide in ambient air have been justified. A high sensitivity of gas chromatographic determination in the range of concentrations (in mg/m3) of 1,3-butadiene, 0,002 - 5, 0, ethylene oxide 0.005 - 1, 0 with 25% uncertainty in the determination has been reached .

摘要

介绍了关于开发气相色谱法的实验研究结果,该方法用于在参考浓度水平下测定环境空气中的1,3 - 丁二烯和环氧乙烷,采用将研究的化合物从环境空气中吸附到吸附剂TenaxTA上,并结合热脱附的最佳条件以及使用毛细管气相色谱法。已经确定了环境空气中1,3 - 丁二烯和环氧乙烷的吸附、热脱附及气相色谱测定参数。在1,3 - 丁二烯浓度范围(mg/m³)为0.002 - 5.0、环氧乙烷浓度范围为0.005 - 1.0时,气相色谱测定具有高灵敏度,测定不确定度为25%。

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