Physics of Complex Fluids, MESA+ Institute, Department of Science and Technology, University of Twente, Enschede, The Netherlands.
J Colloid Interface Sci. 2013 Jan 15;390(1):234-41. doi: 10.1016/j.jcis.2012.08.030. Epub 2012 Oct 2.
We generate and study electroosmotic shear flow in microchannels. By chemically or electrically modifying the surface potential of the channel walls a shear flow component with controllable velocity gradient can be added to the electroosmotic flow caused by double layer effects at the channel walls. Chemical modification is obtained by treating the channel wall with a cationic polymer. In case of electric modification, we used gate electrodes embedded in the channel wall. By applying a voltage to the gate electrode, the zeta potential can be varied and a controllable, uniform shear stress can be applied to the liquid in the channel. The strength of the shear stress depends on both the gate voltage and the applied field which drives the electroosmotic shear flow. Although the stress range is still limited, such a microchannel device can be used in principle as an in situ micro-rheometer for lab on a chip purposes.
我们在微通道中产生并研究电渗流切变流。通过对通道壁的表面电势进行化学或电气修饰,可以在通道壁的双电层效应引起的电渗流中添加具有可控速度梯度的剪切流分量。化学修饰是通过用阳离子聚合物处理通道壁来实现的。在电修饰的情况下,我们使用嵌入在通道壁中的栅极电极。通过向栅极电极施加电压,可以改变 zeta 电势,并可以向通道中的液体施加可控的、均匀的剪切应力。剪切应力的强度取决于栅极电压和驱动电渗切变流的外加电场。尽管应力范围仍然有限,但这样的微通道装置原则上可以用作芯片实验室中的原位微流变仪。